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Alkalinity
and acidity
Alkalinity
and acidity
TBN-TOTAL
BASE NUMBER- measure of alkaline additives available for the neutralisation
of acids from combustion products and oxidation. Level governed by type of
fuel.
For crosshead engines the TBN
will tend to rise due to contamination by liner lubrication, it should not be
allowed to raise more than twice that of the new charge.
As a guide, the TBN of fresh oil should be at least:
·
10 x fuel sulphur content (%) for trunk
piston engines (10mgKOH/g)
·
20 x fuel sulphur content (%) for cyl oil in
x-head engines (20mgKOH/g)
A
simple shipboard go,no-go test is available for measuring the TBN, it involves
the addition of an indicator and acid reagent to a 30ml sample. The quantify of
acid reagent added is determined by the required level of TBN, for TBN2.5 0.5ml
are added, for TBN20 4ml is added. After three minutes the colour is checked
against a chart
·
Purple:Good level of TBN
·
Green:Borderline
·
Yellow:Low level of TBN
TAN-TOTAL
ACID NUMBER-measure of organic acid and strong acid content of oil. Where SAN
is nil, the TAN represents the acidity in the oil due to both the acids in the
additives and the oxidation of the hydrocarbons in the oil. The TAN of fresh
oils varies with oil type, and tends to climb with age. A high TAN may indicate
that an oil should be changed or freshened by top up. A high TAN may be
accompanied with increased viscosity.
SAN-STRONG
ACID NUMBER-indicates the prescience of strong, highly corrosive (inorganic)
acids, usually formed from combustion products. If SAN is non zero the oil
should be changed immediately
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